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		<title>STV ZER910 ZERO in WASP nest Killer Powder Manual</title>
		<link>https://usemanuals.com/stv/zer910-powder/</link>
		
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		<pubDate>Sat, 22 Jul 2023 17:30:22 +0000</pubDate>
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					<description><![CDATA[STV ZER910 ZERO in WASP nest Killer Powder User Manual Identification of the substance/mixture and of the company/undertaking  Product identifier Zero In Wasp Nest Killer Powder Relevant identified uses of the substance or mixture and uses advised against For use as an insecticide Details of the supplier of the safety data sheet STV International Ltd Forge House Little Cressingham Watton Thetford Norfolk IP25 6ND + 44 (0) 1953 881 580 (Office hours only) info@stvpestcontrol.com Emergency telephone number For product information, contact STV International Ltd on the telephone number stated in section 1.3. In the event of a medical enquiry involving this product, please contact your doctor or local hospital accident and emergency department. For urgent medical advice, call the NHS Helpline on 111 (England, Scotland &#38; Wales). For medical emergencies, dial 999 (UK &#38; Ireland) or 112 from any EU country. Hazards identification Classification of the substance or mixture Classification in accordance with Regulation (EC) 1272/2008 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 Label elements Hazard Pictogram GHS09 Signal Word Warning Hazard Statements H410: Very toxic to aquatic life with long lasting effects. Precautionary Statements P102 Keep out of reach of children. P103 Read label before use. P260 Do not breathe dust. P270 Do not eat, drink or smoke when using this product. P262 Do not get in eyes, on skin, or on clothing. P273 Avoid release to the environment. P391 Collect spillage. P501 Dispose of contents/ container in accordance with national regulations. Other labelling required under Regulation (EC) 1272/2008 EUH208: Contains permethrin. May produce an allergic reaction. Other hazards None Composition/information on ingredients Mixtures Substance Name CAS Number EC Number Classification (1272/2008) Concentration (%) Permethrin 52645-53-1 258-067-9 Acute Tox. 4; H302 &#60;1 Acute Tox. 4; H332 Skin Sens. 1; H317 Aquatic Acute 1; H400 M factor Acute = 1000 Aquatic Chronic 1; H410 M factor Chronic = 1000 Disobutyl naphthalene sulphonate, sodium salt 27213-90-7 248-326-4 Skin Irrit. 2; H315 &#60;1 Eye Irrit. 2; H319 Aquatic Chronic 3; H412 For full text of hazard statements, see section 16. First aid measures Description of first aid measures Inhalation Remove affected person from source of contamination. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Get medical attention if any discomfort continues. Skin Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing. Eyes In case of eye contact, rinse eyes immediately with plenty of water. Remove contact lenses if present and open eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention if irritation persists. Ingestion Rinse mouth with water and give water to drink. Do not induce vomiting unless instructed to do so by medical personnel. Never give anything by mouth to an unconscious person. Most important symptoms and effects, both acute and delayed This product is not classified as hazardous to health, therefore no specific symptoms are noted. However, if eye, skin or respiratory irritation persists, or if you are feeling unwell after exposure to the product, seek medical advice. Indication of any immediate medical attention and special treatment needed This product is not classified as hazardous to health, therefore no specific treatment is noted. Treat symptomatically. Firefighting measures Extinguishing media Suitable extinguishing media Water spray, fog or mist. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. Unsuitable extinguishing media Avoid high pressure media Special hazards arising from the substance or mixture None known. The product is non-combustible. Advice for firefighters Use appropriate personal protective equipment to protect skin, eyes and face. Use suitable breathing apparatus to avoid inhalation of dust and hazardous fumes. Run-off from firefighting waters should be contained to avoid release to the environment. Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of dust. In the event of a large spill, area should be evacuated in case of formation of dust clouds. Environmental precautions Do not allow product to enter drains or watercourse. In the case of a large spill, or if a large quantity of product enters the drain or watercourse, contact the Environment Agency or other relevant local authority immediately. Methods and material for containment and cleaning up Collect powder using special dust vacuum cleaner with particle filter or carefully sweep into suitable waste disposal containers and seal securely. Avoid generation and spreading of dust. Reference to other sections See section 8 for personal protective equipment. See section 13 for disposal considerations. Handling and storage Precautions for safe handling Avoid handling which leads to dust formation. Persons susceptible to allergic reactions should not handle this product. Conditions for safe storage, including any incompatibilities Store in tightly-closed, original container in a dry and cool place. Keep separate from food, feed stuffs, fertilisers and other sensitive material. Specific end use(s) For use as an insecticide. Exposure controls/personal protection Control parameters Occupational exposure limits TALC Long-term exposure limit (8-hour TWA): 1 mg/m³ SIPERNAT 50 S TLVs ACGI 10mg/m3 UK EH40/95 3mg/m3 respirable dust, 8 h oes, 6mg/m3 total dust oes. CHINA CLAY Inorganic dust WEL 4mg/m3 resp. dust TWA 8 hrs. Exposure controls Engineering controls Use mechanical ventilation if there is a risk of handling causing formation of airborne dust. Eye/face protection Eye wear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. Respiratory protection Ensure adequate ventilation. Protection against nuisance dust must be used when the airborne concentration exceeds 10 mg/m3. Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible. Environmental exposure controls Do not release to the environment. Physical and chemical properties Information on basic physical and chemical properties Appearance: Grey dusty powder Odour: No characteristic odour Odour threshold: Information not available pH: Information not available Melting point/freezing point: Information not available Initial boiling point and boiling range: Information not available Flash point: Information not available Evaporation rate: Information not available Flammability: Information not available Upper/lower flammability or explosive limits: Information not available Vapour pressure: Information not available Vapour density: Information not available Relative density: Information not available Solubility(ies): Insoluble in water Partition coefficient: n-octanol/water: Information not available Auto-ignition temperature: Information not available Decomposition temperature: Information not available Viscosity: Information not available Explosive properties: Information not available Oxidising properties: Information not available. Other information None Stability and reactivity Reactivity Information not available Chemical stability Stable at normal ambient temperatures and when used as recommended. Possibility of hazardous reactions Hazardous polymerisation will not occur. Conditions to avoid Avoid contact with water. Incompatible materials Information not available. Hazardous decomposition products Does not decompose when used and stored as recommended. Toxicological information Information on toxicological effects Toxicity of product Acute toxicity: Not expected to be toxic. Skin corrosion/irritation: Product is not classified as causing skin corrosion or irritation. Serious eye damage/irritation: Product is not classified as causing serious eye damage or irritation Respiratory or skin sensitisation: Product is not classified as causing skin sensitisation. Germ cell mutagenicity: No information specified. Carcinogenicity: No information specified. Reproductive toxicity: No information specified. STOT-single exposure: No information specified. STOT-repeated exposure: No information specified. Aspiration hazard: No information specified. Toxicity of ingredients Permethrin: LD50 Oral (Rat) 383 mg/kg LC50 Inhalation (Rat) 485 mg/M3 LD50 Dermal (Rabbit) &#62;2000 mg/kg Ecological information Toxicity Toxicity of product The product is very toxic to aquatic life with long lasting effects. Toxicity of ingredients Permethrin: LC50 (Fathead Minow) 96Hr 0.016 mg/L EC50 Daphnia Magna (Water Flea) 48Hr 0.32 µg/L Persistence and degradability The active substance is not readily biodegradable. Bioaccumulative potential Information not available Mobility in soil Information not available Results of PBT and vPvB assessment Information not available Other adverse effects Information not available Disposal considerations Waste treatment methods Disposal methods This material and its container must be disposed of in a safe way. Dispose of in accordance with applicable regional, national, and local laws and regulations. Dispose of contaminated packaging as unused product unless fully cleaned. Transport information UN number 3077 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS PERMETHRIN) Transport hazard class(es) 9  Packing group III Environmental hazards Environmentally hazardous substance/marine pollutant Special precautions for user EmS : F-A, S-F ADR transport category :  3 Emergency Action Code :  2Z Hazard Identification Number (ADR/RID) :  90 Tunnel restriction code :  (E) Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture This mixture has been classified in accordance with Regulation (EC) 1272/2008. This product is authorised in accordance with the Control of Pesticides Regulations 1986 (as amended). This product is subject to The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009. This safety data sheet has been compiled in accordance with Regulation (EC) 1906/2006 as amended by Regulation (EU) 2015/830. Chemical safety assessment No chemical safety assessment has been carried out. Other information Abbreviations and acronyms PBT – Persistent, Bioaccumulative and Toxic vPvB – Very persistent and very Bioaccumulative Full text of hazard statements listed in section 3 H302: Harmful if swallowed H332: Harmful if inhaled H317: May cause an allergic skin reaction H400: Very toxic to aquatic life H410: Very toxic to aquatic life with long lasting effects H315: Causes skin irritation H319: Causes serious eye irritation H412: Harmful to aquatic life with long lasting effects Comments Use only in accordance with label instructions. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by legislation. The information in this data sheet should be considered when undertaking a risk assessment under the COSHH regulations. The information contained within this data sheet is strictly for general guidance only and should not be relied upon over and above this. This data sheet is intended to provide general health and safety guidance on the storage and transportation of the preparation. The information in this data sheet is accurate at the date of publication and will be updated as and when appropriate. No liability will be accepted by STV International Ltd for any loss, injury or damage arising from any failure to comply with the information and advice contained within this data sheet and/or failure to comply with the manufacturer’s guidelines, product label data and any associated technical usage literature. [...]<p><a class="btn btn-secondary understrap-read-more-link" href="https://usemanuals.com/stv/zer910-powder/">Read More...</a></p>]]></description>
										<content:encoded><![CDATA[<p><strong>STV ZER910 ZERO in WASP nest Killer Powder User Manual<br />
<img decoding="async" src="https://usemanuals.com/wp-content/uploads/2023/07/image-Copy-179-260x300-1.webp" /><br />
</strong></p>
<h4>Identification of the substance/mixture and of the company/undertaking</h4>
<h5> Product identifier</h5>
<p>Zero In Wasp Nest Killer Powder</p>
<p><strong>Relevant identified uses of the substance or mixture and uses advised against</strong></p>
<p>For use as an insecticide</p>
<h5>Details of the supplier of the safety data sheet</h5>
<ul>
<li>STV International Ltd</li>
<li>Forge House</li>
<li>Little Cressingham</li>
<li>Watton</li>
<li>Thetford</li>
<li>Norfolk</li>
<li>IP25 6ND</li>
</ul>
<p><strong>+ 44 (0) 1953 881 580</strong> (Office hours only)<br />
<a href="mailto:info@stvpestcontrol.com">info@stvpestcontrol.com</a></p>
<h5><strong>Emergency telephone number</strong></h5>
<p>For product information, contact STV International Ltd on the telephone number stated in section 1.3.</p>
<p>In the event of a medical enquiry involving this product, please contact your doctor or local hospital accident and emergency department.</p>
<p>For urgent medical advice, call the NHS Helpline on 111 (England, Scotland &amp; Wales).<br />
For medical emergencies, dial 999 (UK &amp; Ireland) or 112 from any EU country.</p>
<h4>Hazards identification</h4>
<h5><strong>Classification of the substance or mixture</strong></h5>
<p>Classification in accordance with Regulation (EC) 1272/2008</p>
<ol>
<li>Aquatic Acute 1; H400</li>
<li>Aquatic Chronic 1; H410</li>
</ol>
<p><strong>Label elements</strong></p>
<p><strong>Hazard Pictogram</strong></p>
<ul>
<li><strong>GHS09<br />
<img decoding="async" src="https://usemanuals.com/wp-content/uploads/2023/07/1-645-300x281-1.webp" /><br />
</strong></li>
</ul>
<p><strong>Signal Word</strong></p>
<ul>
<li>Warning</li>
</ul>
<p><strong>Hazard Statements</strong></p>
<ul>
<li><strong>H410:</strong> Very toxic to aquatic life with long lasting effects.</li>
</ul>
<p><strong>Precautionary Statements</strong></p>
<ul>
<li>P102 Keep out of reach of children.</li>
<li>P103 Read label before use.</li>
<li>P260 Do not breathe dust.</li>
<li>P270 Do not eat, drink or smoke when using this product. P262 Do not get in eyes, on skin, or on clothing.</li>
<li>P273 Avoid release to the environment.</li>
<li>P391 Collect spillage.</li>
<li>P501 Dispose of contents/ container in accordance with national regulations.</li>
</ul>
<p><strong>Other labelling required under Regulation (EC) 1272/2008</strong></p>
<ul>
<li><strong>EUH208:</strong> Contains permethrin. May produce an allergic reaction.</li>
</ul>
<h5>Other hazards</h5>
<ul>
<li>None</li>
</ul>
<h4>Composition/information on ingredients</h4>
<h5>Mixtures</h5>
<table>
<tbody>
<tr>
<td width="128">Substance Name</td>
<td width="128">CAS Number</td>
<td width="128">EC Number</td>
<td width="128">Classification (1272/2008)</td>
<td width="128">Concentration (%)</td>
</tr>
<tr>
<td rowspan="7" width="128">Permethrin</td>
<td rowspan="7" width="128">52645-53-1</td>
<td rowspan="7" width="128">258-067-9</td>
<td width="128">Acute Tox. 4; H302</td>
<td rowspan="7" width="128">&lt;1</td>
</tr>
<tr>
<td width="128">Acute Tox. 4; H332</td>
</tr>
<tr>
<td width="128">Skin Sens. 1; H317</td>
</tr>
<tr>
<td width="128">Aquatic Acute 1; H400</td>
</tr>
<tr>
<td width="128">M factor Acute = 1000</td>
</tr>
<tr>
<td width="128">Aquatic Chronic 1; H410</td>
</tr>
<tr>
<td width="128">M factor Chronic = 1000</td>
</tr>
<tr>
<td rowspan="3" width="128">Disobutyl naphthalene sulphonate, sodium salt</td>
<td rowspan="3" width="128">27213-90-7</td>
<td rowspan="3" width="128">248-326-4</td>
<td width="128">Skin Irrit. 2; H315</td>
<td rowspan="3" width="128">&lt;1</td>
</tr>
<tr>
<td width="128">Eye Irrit. 2; H319</td>
</tr>
<tr>
<td width="128">Aquatic Chronic 3; H412</td>
</tr>
</tbody>
</table>
<p>For full text of hazard statements, see section 16.</p>
<h4>First aid measures</h4>
<h5>Description of first aid measures</h5>
<p><strong>Inhalation</strong></p>
<p>Remove affected person from source of contamination. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Get medical attention if any discomfort continues.</p>
<p><strong>Skin</strong></p>
<p>Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing.</p>
<p><strong>Eyes</strong></p>
<p>In case of eye contact, rinse eyes immediately with plenty of water.<br />
Remove contact lenses if present and open eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention if irritation persists.</p>
<p><strong>Ingestion</strong></p>
<p>Rinse mouth with water and give water to drink. Do not induce vomiting unless instructed to do so by medical personnel. Never give anything by mouth to an unconscious person.</p>
<h5>Most important symptoms and effects, both acute and delayed</h5>
<p>This product is not classified as hazardous to health, therefore no specific symptoms are noted.<br />
However, if eye, skin or respiratory irritation persists, or if you are feeling unwell after exposure to the product, seek medical advice.</p>
<p><strong>Indication of any immediate medical attention and special treatment needed</strong></p>
<p>This product is not classified as hazardous to health, therefore no specific treatment is noted. Treat symptomatically.</p>
<h4>Firefighting measures</h4>
<h5>Extinguishing media</h5>
<p><strong>Suitable extinguishing media</strong></p>
<ul>
<li>Water spray, fog or mist.</li>
<li>Carbon dioxide (CO2).</li>
<li>Dry chemicals, sand, dolomite etc.</li>
</ul>
<p><strong>Unsuitable extinguishing media</strong></p>
<ul>
<li>Avoid high pressure media</li>
</ul>
<p><strong>Special hazards arising from the substance or mixture</strong></p>
<p>None known. The product is non-combustible.</p>
<p><strong>Advice for firefighters</strong></p>
<p>Use appropriate personal protective equipment to protect skin, eyes and face. Use suitable breathing apparatus to avoid inhalation of dust and hazardous fumes.<br />
Run-off from firefighting waters should be contained to avoid release to the environment.</p>
<h4>Accidental release measures</h4>
<h5>Personal precautions, protective equipment and emergency procedures</h5>
<p>Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of dust.<br />
In the event of a large spill, area should be evacuated in case of formation of dust clouds.</p>
<h5>Environmental precautions</h5>
<p>Do not allow product to enter drains or watercourse. In the case of a large spill, or if a large quantity of product enters the drain or watercourse, contact the Environment Agency or other relevant local authority immediately.</p>
<p><strong>Methods and material for containment and cleaning up</strong></p>
<p>Collect powder using special dust vacuum cleaner with particle filter or carefully sweep into suitable waste disposal containers and seal securely. Avoid generation and spreading of dust.</p>
<p><strong>Reference to other sections</strong></p>
<ul>
<li>See section 8 for personal protective equipment.</li>
<li>See section 13 for disposal considerations.</li>
</ul>
<h4>Handling and storage</h4>
<p><strong>Precautions for safe handling</strong></p>
<p>Avoid handling which leads to dust formation. Persons susceptible to allergic reactions should not handle this product.</p>
<p><strong>Conditions for safe storage, including any incompatibilities</strong></p>
<p>Store in tightly-closed, original container in a dry and cool place. Keep separate from food, feed stuffs, fertilisers and other sensitive material.</p>
<h5>Specific end use(s)</h5>
<p>For use as an insecticide.</p>
<h4>Exposure controls/personal protection</h4>
<h5>Control parameters</h5>
<p><strong>Occupational exposure limits</strong></p>
<ul>
<li><strong>TALC</strong><br />
Long-term exposure limit (8-hour TWA): 1 mg/m³</li>
<li><strong>SIPERNAT 50 S</strong></li>
<li>TLVs ACGI 10mg/m3 UK EH40/95 3mg/m3 respirable dust, 8 h oes, 6mg/m3 total dust oes.</li>
<li><strong>CHINA CLAY</strong><br />
Inorganic dust WEL 4mg/m3 resp. dust TWA 8 hrs.</li>
</ul>
<h5>Exposure controls</h5>
<p><strong>Engineering controls</strong></p>
<p>Use mechanical ventilation if there is a risk of handling causing formation of airborne dust.</p>
<p><strong>Eye/face protection</strong></p>
<p>Eye wear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible.</p>
<p><strong>Hand protection</strong></p>
<p>Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible.</p>
<p><strong>Respiratory protection</strong></p>
<p>Ensure adequate ventilation. Protection against nuisance dust must be used when the airborne concentration exceeds 10 mg/m3. Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible.</p>
<p><strong>Environmental exposure controls</strong></p>
<p>Do not release to the environment.</p>
<h4>Physical and chemical properties</h4>
<h5>Information on basic physical and chemical properties</h5>
<ul>
<li><strong>Appearance:</strong> Grey dusty powder</li>
<li><strong>Odour:</strong> No characteristic odour</li>
<li>Odour threshold: Information not available</li>
<li><strong>pH:</strong> Information not available</li>
<li><strong>Melting point/freezing point:</strong> Information not available</li>
<li><strong>Initial boiling point and boiling range:</strong> Information not available</li>
<li><strong>Flash point:</strong> Information not available</li>
<li><strong>Evaporation rate:</strong> Information not available</li>
<li><strong>Flammability:</strong> Information not available</li>
<li><strong>Upper/lower flammability or explosive limits:</strong> Information not available</li>
<li><strong>Vapour pressure:</strong> Information not available</li>
<li><strong>Vapour density:</strong> Information not available</li>
<li><strong>Relative density:</strong> Information not available</li>
<li><strong>Solubility(ies):</strong> Insoluble in water</li>
<li><strong>Partition coefficient: n-octanol/water:</strong> Information not available</li>
<li><strong>Auto-ignition temperature:</strong> Information not available</li>
<li><strong>Decomposition temperature:</strong> Information not available</li>
<li><strong>Viscosity:</strong> Information not available</li>
<li><strong>Explosive properties:</strong> Information not available</li>
<li><strong>Oxidising properties:</strong> Information not available.</li>
</ul>
<p><strong>Other information</strong></p>
<p>None</p>
<h4>Stability and reactivity</h4>
<h5>Reactivity</h5>
<p>Information not available</p>
<p><strong>Chemical stability</strong></p>
<p>Stable at normal ambient temperatures and when used as recommended.</p>
<p><strong>Possibility of hazardous reactions</strong></p>
<p>Hazardous polymerisation will not occur.</p>
<p><strong>Conditions to avoid</strong></p>
<p>Avoid contact with water.</p>
<p><strong>Incompatible materials</strong></p>
<p>Information not available.</p>
<p><strong>Hazardous decomposition products</strong></p>
<p>Does not decompose when used and stored as recommended.</p>
<h4>Toxicological information</h4>
<h5>Information on toxicological effects</h5>
<p><strong>Toxicity of product</strong></p>
<ul>
<li><strong>Acute toxicity:</strong> Not expected to be toxic.</li>
<li><strong>Skin corrosion/irritation:</strong> Product is not classified as causing skin corrosion or irritation.</li>
<li><strong>Serious eye damage/irritation:</strong> Product is not classified as causing serious eye damage or irritation</li>
<li><strong>Respiratory or skin sensitisation:</strong> Product is not classified as causing skin sensitisation.</li>
<li><strong>Germ cell mutagenicity:</strong> No information specified.</li>
<li><strong>Carcinogenicity:</strong> No information specified.</li>
<li><strong>Reproductive toxicity:</strong> No information specified.</li>
<li><strong>STOT-single exposure:</strong> No information specified.</li>
<li><strong>STOT-repeated exposure:</strong> No information specified.</li>
<li><strong>Aspiration hazard:</strong> No information specified.</li>
</ul>
<p><strong>Toxicity of ingredients</strong></p>
<p><strong>Permethrin:</strong></p>
<ol>
<li>LD50 Oral (Rat) 383 mg/kg</li>
<li>LC50 Inhalation (Rat) 485 mg/M3</li>
<li>LD50 Dermal (Rabbit) &gt;2000 mg/kg</li>
</ol>
<h4>Ecological information</h4>
<h5>Toxicity</h5>
<p><strong>Toxicity of product</strong></p>
<p>The product is very toxic to aquatic life with long lasting effects.</p>
<p><strong>Toxicity of ingredients</strong></p>
<p><strong>Permethrin:</strong></p>
<ol>
<li>LC50 (Fathead Minow) 96Hr 0.016 mg/L</li>
<li>EC50 Daphnia Magna (Water Flea) 48Hr 0.32 µg/L</li>
</ol>
<p><strong>Persistence and degradability</strong></p>
<p>The active substance is not readily biodegradable.</p>
<p><strong>Bioaccumulative potential</strong></p>
<p>Information not available</p>
<p><strong>Mobility in soil</strong></p>
<p>Information not available</p>
<p><strong>Results of PBT and vPvB assessment</strong></p>
<p>Information not available</p>
<p><strong>Other adverse effects</strong></p>
<p>Information not available</p>
<h4>Disposal considerations</h4>
<h5>Waste treatment methods</h5>
<p><strong>Disposal methods</strong></p>
<p>This material and its container must be disposed of in a safe way. Dispose of in accordance with applicable regional, national, and local laws and regulations.<br />
Dispose of contaminated packaging as unused product unless fully cleaned.</p>
<p><strong>Transport information</strong></p>
<p><strong>UN number</strong></p>
<ul>
<li>3077</li>
</ul>
<p><strong>UN proper shipping name</strong></p>
<p>ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS PERMETHRIN)</p>
<p>Transport hazard class(es)</p>
<ul>
<li>9</li>
</ul>
<h5> Packing group</h5>
<ul>
<li>III</li>
</ul>
<p><strong>Environmental hazards</strong></p>
<p>Environmentally hazardous substance/marine pollutant<br />
<img decoding="async" src="https://usemanuals.com/wp-content/uploads/2023/07/1-645-300x281-2.webp" /></p>
<p><strong>Special precautions for user</strong></p>
<ul>
<li><strong>EmS :</strong> F-A, S-F</li>
<li><strong>ADR transport category : </strong> 3</li>
<li><strong>Emergency Action Code :</strong>  2Z</li>
<li><strong>Hazard Identification Number (ADR/RID) :</strong>  90</li>
<li><strong>Tunnel restriction code : </strong> (E)</li>
</ul>
<p><strong>Transport in bulk according to Annex II of Marpol and the IBC Code</strong></p>
<p>Not applicable.</p>
<h4>Regulatory information</h4>
<p><strong>Safety, health and environmental regulations/legislation specific for the substance or mixture</strong></p>
<p>This mixture has been classified in accordance with Regulation (EC) 1272/2008.<br />
This product is authorised in accordance with the Control of Pesticides Regulations 1986 (as amended).<br />
This product is subject to The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009.<br />
This safety data sheet has been compiled in accordance with Regulation (EC) 1906/2006 as amended by Regulation (EU) 2015/830.</p>
<p><strong>Chemical safety assessment</strong></p>
<p>No chemical safety assessment has been carried out.</p>
<h4>Other information</h4>
<p><strong>Abbreviations and acronyms</strong></p>
<ul>
<li>PBT – Persistent, Bioaccumulative and Toxic</li>
<li>vPvB – Very persistent and very Bioaccumulative</li>
</ul>
<p><strong>Full text of hazard statements listed in section 3</strong></p>
<ol>
<li><strong>H302:</strong> Harmful if swallowed</li>
<li><strong>H332:</strong> Harmful if inhaled</li>
<li><strong>H317:</strong> May cause an allergic skin reaction</li>
<li><strong>H400:</strong> Very toxic to aquatic life</li>
<li><strong>H410:</strong> Very toxic to aquatic life with long lasting effects</li>
<li><strong>H315:</strong> Causes skin irritation</li>
<li><strong>H319:</strong> Causes serious eye irritation</li>
<li><strong>H412:</strong> Harmful to aquatic life with long lasting effects</li>
</ol>
<p><strong>Comments</strong></p>
<p>Use only in accordance with label instructions.<br />
The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by legislation. The information in this data sheet should be considered when undertaking a risk assessment under the COSHH regulations.<br />
The information contained within this data sheet is strictly for general guidance only and should not be relied upon over and above this. This data sheet is intended to provide general health and safety guidance on the storage and transportation of the preparation.<br />
The information in this data sheet is accurate at the date of publication and will be updated as and when appropriate. No liability will be accepted by STV International Ltd for any loss, injury or damage arising from any failure to comply with the information and advice contained within this data sheet and/or failure to comply with the manufacturer’s guidelines, product label data and any associated technical usage literature.</p>
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		<item>
		<title>STV ZER962 Live Pes-Free ANT and Crawling Insect Killer Manual</title>
		<link>https://usemanuals.com/stv/zer962-killer/</link>
		
		<dc:creator><![CDATA[ItsManual]]></dc:creator>
		<pubDate>Sat, 22 Jul 2023 17:37:32 +0000</pubDate>
				<category><![CDATA[STV]]></category>
		<guid isPermaLink="false">https://usemanuals.com/?p=171517</guid>

					<description><![CDATA[STV ZER962 Live Pes-Free ANT and Crawling Insect Killer User Manual SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Zero In Ant &#38; Crawling Insect Killer 1.2. Relevant identified uses of the substance or mixture and uses advised against For use as an insecticide 1.3. Details of the supplier of the safety data sheet STV International Ltd Forge House Little Cress Ingham Watton Thetford Norfolk IP25 6ND + 44 (0) 1953 881 580 (Office hours only) info@stvpestcontrol.com 1.4. Emergency telephone number For product information, contact STV International Ltd on the telephone number stated in section 1.3. In the event of a medical enquiry involving this product, please contact your doctor or local hospital accident and emergency department. For urgent medical advice, call the NHS Helpline on 111 (England, Scotland &#38; Wales). For medical emergencies, dial 999 (UK &#38; Ireland) or 112 from any EU country. Environmental agency emergency phone number 0800 807060. SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Flam. Aerosol 1; H222, H229 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 2.2. Label elements GHS02, GHS09 Danger H222: Extremely flammable aerosol. H229: Pressurized container: May burst if heated. H410: Very toxic to aquatic life with long lasting effects. P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children P103 Read label before use P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. P501 Dispose of contents/container in accordance with local/national regulations. EUH208: Contains permethrin. May produce an allergic reaction. 2.3. Other hazards This mixture does not meet the criteria for PBT or vPvB in accordance with Annex XIII of Regulation (EC) No 1907/2006 (REACH). SECTION 3: Composition/information on ingredients 3.1. Mixtures SECTION 4: First aid measures 4.1. Description of first aid measures This product is not considered to be hazardous to human health. However, if exposure occurs, the following first aid measures should be followed: Move exposed person to fresh air. If breathing discomfort occurs, seek medical attention. Wash contaminated skin with plenty of soap and water. Seek medical attention if skin irritation occurs. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Seek medical attention if eye irritation occurs. Wash out mouth with water. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. 4.2. Most important symptoms and effects, both acute and delayed Inhalation – Vapors may cause headache, fatigue, dizziness and nausea. Ingestion – Gastrointestinal symptoms, including upset stomach. Skin contact ­ The product contains a sensitizing substance. Eye contact- May cause discomfort. 4.3. Indication of any immediate medical attention and special treatment needed No specific advice. Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Extinguish with foam, carbon dioxide or dry powder. Not applicable. 5.2. Special hazards arising from the substance or mixture Extremely flammable aerosol. Pressurized container: may burst if heated. Thermal decomposition or combustion products may include the following substances: Ammonia or amines. Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx). 5.3. Advice for firefighters Cool containers exposed to flames with water until well after the fire is out. Wear protective clothing to prevent contact with skin and eyes. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots, clothing or apron, as appropriate. Do not touch or walk into spilled material. No smoking, sparks, flames or other sources of ignition near spillage. Avoid contact with skin, eyes and clothing. Avoid inhalation of vapors. Provide adequate ventilation. If aerosol cans are ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. Avoid contact with contaminated tools and objects. Take care as floors and other surfaces may become slippery. Do not handle broken packages without protective equipment. Wash thoroughly after dealing with a spillage. 6.2. Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Environmental agency emergency phone number 0800 807060. 6.3. Methods and material for containment and cleaning up Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots, clothing or apron, as appropriate. Eliminate all sources of ignition. Provide adequate ventilation. Absorb spillage with inert, damp, non-combustible material. Collect and place in suitable waste disposal containers and seal securely. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. 6.4. Reference to other sections See section 1 for emergency contact information. See section 8 for information on appropriate personal protective equipment. See section 13 for additional waste treatment information. SECTION 7: Handling and storage 7.1. Precautions for safe handling To avoid risks to human health and the environment, comply with the instructions for use. Use biocides safely. Always read the label and product information before use. Wear protective gloves. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Provide adequate ventilation. Keep container in a well-ventilated place. Avoid contact with skin, eyes and clothing. Avoid breathing vapor/spray. Do not expose to temperatures exceeding 50°C/122°F. Do not spray on an open flame or other ignition source. Keep out of the reach of children. Do not pierce or burn, even after use. Do not empty into drains. Do not eat, drink or smoke when using this product. Avoid contact with contaminated tools and objects. Do not handle broken packages without protective equipment. Wash hands thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Store at temperatures between 4°C and 40°C. Do not expose to temperatures exceeding 50°C/122°F. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep out of the reach of children. Storage class Flammable compressed gas storage. 7.3. Specific end use(s) For use as an insecticide SECTION 8: Exposure controls/personal protection 8.1. Control parameters PERMETHRIN (CAS: 52645-53-1) DNEL – Oral; : 16.7 – 120 mg/kg PNEC – Fresh water; 0.00000047 mg/l – STP; 0.00495 mg/l – Soil; &#62;0.0876 mg/kg – Sediment (Freshwater); 0.01 mg/kg 8.2. Exposure controls If user operations generate dust, fumes, gas, vapor or mist use Process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended statutory limits. Eye/face protection not normally required. Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Tight-fitting safety glasses. Personal protective equipment for eye and face protection should comply with European Standard EN166. Hand protection not normally required. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. After contamination with product change gloves immediately and dispose of them according to relevant national and local regulations. Recommended : (&#60;1 hour) PVC , Nitrile gloves. No personal respiratory protective equipment normally required. Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Always follow respirator manufacturer’s instructions regarding wearing and maintenance. Recommended: Full mask with type ABEK filter. Steps should be taken to ensure that this product is not released accidentally into the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance: Colorless aerosol Odour: Characteristic Odour threshold: Information not available pH: Information not available Melting point/freezing point: Information not available Initial boiling point and boiling range: Information not available Flash point: Information not available Evaporation rate: Information not available Flammability: Extremely flammable aerosol Upper/lower flammability or explosive limits: Information not available Vapor pressure: Information not available Vapor density: Information not available Relative density: Information not available Solubility(ies): Information not available Partition coefficient: n-octanol/water: Information not available Auto-ignition temperature: Information not available Decomposition temperature: Information not available Viscosity: Information not available Explosive properties: Information not available Oxidizing properties: Information not available 9.2. Other information None SECTION 10: Stability and reactivity 10.1. Reactivity There are no known reactivity hazards associated with this product. 10.2. Chemical stability Product is stable under normal storage and handling conditions. 10.3. Possibility of hazardous reactions Not determined. 10.4. Conditions to avoid Avoid heat, flames and other sources of ignition. 10.5. Incompatible materials No specific material or group of materials is likely to react with the product to produce a hazardous situation. 10.6. Hazardous decomposition products Thermal decomposition or combustion products may include the following substances: Ammonia or amines. Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx). SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity: Not expected to be toxic. Skin corrosion/irritation: Product is not classified as causing skin corrosion or irritation. Serious eye damage/irritation: Product is not classified as causing serious eye damage or irritation Respiratory or skin sensitization: The product contains a sensitizing substance. Vapors may cause headache, fatigue, dizziness and nausea Germ cell mutagenicity: No information specified. Carcinogenicity: No information specified. Reproductive toxicity: No information specified. STOT-single exposure: No information specified. STOT-repeated exposure: No information specified. Aspiration hazard: No information specified. TETRAMETHRIN Acute toxicity – oral Acute toxicity oral (LD mg/kg) 2,000.0 Species Rat Acute toxicity – dermal Acute toxicity dermal (LD mg/kg) 2,000.0 Species Rat PERMETHRIN Acute toxicity – oral Acute toxicity oral (LD mg/kg) 554.0 Species Rat ATE oral (mg/kg) 554.0 Acute toxicity – dermal Acute toxicity dermal (LD mg/kg) 2,000.1 Species Rat ATE dermal (mg/kg) 2,000.1 Acute toxicity – inhalation Acute toxicity inhalation (LC dust/mist mg/l) 4.638 Species Rat ATE inhalation (dusts/mists mg/l) 4.638 SECTION 12: Ecological information 12.1. Toxicity This product is classified as very toxic to aquatic life with long lasting effects. PIPERONYL BUTOXIDE Acute aquatic toxicity LE(C)₅₀ 0.1 &#60; L(E)C50 ≤ 1 M factor (Acute) 1 Chronic aquatic toxicity M factor (Chronic) 1 ATETRAMETHRIN Acute aquatic toxicity LE(C)₅₀ 0.1 &#60; L(E)C50 ≤ 1 M factor (Acute) 1 Acute toxicity – fish LC50, 96 hours: 0.033 mg/l, Brach danio reroof (Zebra Fish) Acute toxicity – aquatic invertebrates EC₅₀, 48 hours: 0.47 mg/l, Daphnia magna Acute toxicity – aquatic plants IC₅₀, 72 hours: 1.36 mg/l, Scenedesmus subspicatus Chronic aquatic toxicity NOEC 0.001 &#60; NOEC ≤ 0.01 Degradability Non-rapidly degradable M factor (Chronic) 10 PERMETHRIN Acute aquatic toxicity LE(C)₅₀ 0.001 &#60; L(E)C50 ≤ 0.01 M factor (Acute) 100 Acute toxicity – fish LC50, 96 hours: 0.0089 mg/l, Poecilia reticulata (Guppy) LC50, 96 hours: 0.145 mg/l, Cyprinus carpio (Common carp) Acute toxicity – aquatic invertebrates EC₅₀, 48 hours: 0.02 mg/l, Daphnia magna Chronic aquatic toxicity NOEC 0.00001 &#60; NOEC ≤ 0.0001 Degradability Non-rapidly degradable M factor (Chronic) 1000 12.2. Persistence and degradability The product is expected to be biodegradable. 12.3. Bioaccumulate potential The product does not contain any substances expected to be bioaccumulating. 12.4. Mobility in soil Information not available 12.5. Results of PBT and vPvB assessment This product is not identified as a PBT/vPvB substance. 12.6. Other adverse effects Information not available SECTION 13: Disposal considerations 13.1. Waste treatment methods Dispose of contents/container in accordance with all local, regional, national and international regulations. SECTION 14: Transport information 14.1. UN number UN1950 14.2. UN proper shipping name AEROSOLS 14.3. Transport hazard class(es) 2.1 14.4. Packing group Not applicable. 14.5. Environmental hazards Environmentally hazardous substance/marine pollutant 14.6. Special precautions for user Tunnel restriction code (D) 14.7. Transport in bulk according to Annex II of Marol and the IBC Code Not applicable. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture This substance is classified and labelled in accordance with Regulation (EC) 1272/2008 and Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. 15.2. Chemical safety assessment A Chemical Safety Assessment has not been carried out. SECTION 16: Other information ATE: Acute Toxicity Estimate. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. CAS: Chemical Abstracts Service. DNEL: Derived No Effect Level. EC₅₀: 50% of maximal Effective Concentration. IATA: International Air Transport Association. ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air. IMDG: International Maritime Dangerous Goods. LC₅₀: Lethal Concentration to 50 % of a test population. LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose). NOEC: No Observed Effect Concentration. PBT: Persistent, Bioaccumulate and Toxic substance. PNEC: Predicted No Effect Concentration. REACH: Registration, Evaluation, Authorization and Restriction of Chemicals Regulation (EC) No 1907/2006. UN: United Nations. vPvB: Very Persistent and Very Bioaccumulate Acute Tox. = Acute toxicity Aerosol = Aerosol Aquatic Acute = Hazardous to the aquatic environment (acute) Aquatic Chronic = Hazardous to the aquatic environment (chronic) Asp. Tox. = Aspiration hazard Press. Gas (Comp.) = Gas under pressure: Compressed gas Skin Sens. = Skin sensitization STOT SE = Specific target organ toxicity-single exposure H220 Extremely flammable gas. H222 Extremely flammable aerosol. H229 Pressurized container: may burst if heated. H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Use only in accordance with label instructions. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by legislation. The information in this data sheet should be considered when undertaking a risk assessment under the COSHH regulations. The information contained within this data sheet is strictly for general guidance only and should not be relied upon over and above this. This data sheet is intended to provide general health and safety guidance on the storage and transportation of the preparation. The information in this data sheet is accurate at the date of publication and will be updated as and when appropriate. No liability will be accepted by STV International Ltd for any loss, injury or damage arising from any failure to comply with the information and advice contained within this data sheet and/or failure to comply with the manufacturer’s guidelines, product label data and any associated technical usage literature [...]<p><a class="btn btn-secondary understrap-read-more-link" href="https://usemanuals.com/stv/zer962-killer/">Read More...</a></p>]]></description>
										<content:encoded><![CDATA[<pre><em><strong>STV ZER962 Live Pes-Free ANT and Crawling</strong></em></pre>
<pre><em><strong> Insect Killer User Manual</strong></em></pre>
<p><img decoding="async" src="https://usemanuals.com/wp-content/uploads/2023/07/STV-ZER962-Live-Pes-Free-ANT-and-Crawling-Insect-Killer-User-Manual.webp" /></p>
<h4>SECTION 1: Identification of the substance/mixture and of the company/undertaking</h4>
<h5>1.1. Product identifier</h5>
<p>Zero In Ant &amp; Crawling Insect Killer</p>
<h5>1.2. Relevant identified uses of the substance or mixture and uses advised against</h5>
<p>For use as an insecticide</p>
<h5>1.3. Details of the supplier of the safety data sheet</h5>
<p>STV International Ltd<br />
Forge House<br />
Little Cress Ingham<br />
Watton<br />
Thetford<br />
Norfolk<br />
IP25 6ND<br />
+ 44 (0) 1953 881 580 (Office hours only) <a href="mailto:info@stvpestcontrol.com">info@stvpestcontrol.com</a></p>
<h5>1.4. Emergency telephone number</h5>
<p>For product information, contact STV International Ltd on the telephone number stated in section 1.3.<br />
In the event of a medical enquiry involving this product, please contact your doctor or local hospital accident and emergency department.<br />
For urgent medical advice, call the NHS Helpline on 111 (England, Scotland &amp; Wales). For medical emergencies, dial 999 (UK &amp; Ireland) or 112 from any EU country.<br />
Environmental agency emergency phone number 0800 807060.</p>
<h4>SECTION 2: Hazards identification</h4>
<h5>2.1. Classification of the substance or mixture</h5>
<p>Flam. Aerosol 1; H222, H229 Aquatic Acute 1; H400</p>
<p>Aquatic Chronic 1; H410</p>
<h5>2.2. Label elements</h5>
<p>GHS02, GHS09</p>
<p><img decoding="async" src="https://usemanuals.com/wp-content/uploads/2023/07/STV-ZER962-Live-Pes-Free-ANT-and-Crawling-Insect-Killer-User-Manual-Hazard-Pictograms-icons.webp" /></p>
<p>Danger</p>
<p>H222: Extremely flammable aerosol.<br />
H229: Pressurized container: May burst if heated.<br />
H410: Very toxic to aquatic life with long lasting effects.</p>
<p>P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children<br />
P103 Read label before use<br />
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.<br />
P211 Do not spray on an open flame or other ignition source.<br />
P251 Do not pierce or burn, even after use.<br />
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.<br />
P501 Dispose of contents/container in accordance with local/national regulations.</p>
<p>EUH208: Contains permethrin. May produce an allergic reaction.</p>
<h5>2.3. Other hazards</h5>
<p>This mixture does not meet the criteria for PBT or vPvB in accordance with Annex XIII of Regulation (EC) No 1907/2006 (REACH).</p>
<h4>SECTION 3: Composition/information on ingredients</h4>
<h5>3.1. Mixtures</h5>
<p><img decoding="async" src="https://usemanuals.com/wp-content/uploads/2023/07/STV-ZER962-Live-Pes-Free-ANT-and-Crawling-Insect-Killer-User-Manual-Mixtures-1.webp" /><img decoding="async" src="https://usemanuals.com/wp-content/uploads/2023/07/STV-ZER962-Live-Pes-Free-ANT-and-Crawling-Insect-Killer-User-Manual-Mixtures-2.webp" /></p>
<h4>SECTION 4: First aid measures</h4>
<h5>4.1. Description of first aid measures</h5>
<p>This product is not considered to be hazardous to human health. However, if exposure occurs, the following first aid measures should be followed:</p>
<p>Move exposed person to fresh air. If breathing discomfort occurs, seek medical attention.</p>
<p>Wash contaminated skin with plenty of soap and water. Seek medical attention if skin irritation occurs.</p>
<p>Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Seek medical attention if eye irritation occurs.</p>
<p>Wash out mouth with water. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.</p>
<h5>4.2. Most important symptoms and effects, both acute and delayed</h5>
<p>Inhalation – Vapors may cause headache, fatigue, dizziness and nausea. Ingestion – Gastrointestinal symptoms, including upset stomach. Skin contact ­ The product contains a sensitizing substance.<br />
Eye contact- May cause discomfort.</p>
<h5>4.3. Indication of any immediate medical attention and special treatment needed</h5>
<p>No specific advice. Treat symptomatically.</p>
<h4>SECTION 5: Firefighting measures</h4>
<h5>5.1. Extinguishing media</h5>
<p>Extinguish with foam, carbon dioxide or dry powder.</p>
<p>Not applicable.</p>
<h5>5.2. Special hazards arising from the substance or mixture</h5>
<p>Extremely flammable aerosol. Pressurized container: may burst if heated. Thermal decomposition or combustion products may include the following substances: Ammonia or amines. Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx).</p>
<h5>5.3. Advice for firefighters</h5>
<p>Cool containers exposed to flames with water until well after the fire is out. Wear protective clothing to prevent contact with skin and eyes. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.</p>
<h4>SECTION 6: Accidental release measures</h4>
<h5>6.1. Personal precautions, protective equipment and emergency procedures</h5>
<p>Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots, clothing or apron, as appropriate. Do not touch or walk into spilled material. No smoking, sparks, flames or other sources of ignition near spillage. Avoid contact with skin, eyes and clothing. Avoid inhalation of vapors. Provide adequate ventilation. If aerosol cans are ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. Avoid contact with contaminated tools and objects. Take care as floors and other surfaces may become slippery. Do not handle broken packages without protective equipment. Wash thoroughly after dealing with a spillage.</p>
<h5>6.2. Environmental precautions</h5>
<p>Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Environmental agency emergency phone number 0800 807060.</p>
<h5>6.3. Methods and material for containment and cleaning up</h5>
<p>Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots, clothing or apron, as appropriate. Eliminate all sources of ignition. Provide adequate ventilation. Absorb spillage with inert, damp, non-combustible material. Collect and place in suitable waste disposal containers and seal securely. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage.</p>
<h5>6.4. Reference to other sections</h5>
<p>See section 1 for emergency contact information. See section 8 for information on appropriate personal protective equipment. See section 13 for additional waste treatment information.</p>
<h4>SECTION 7: Handling and storage</h4>
<h5>7.1. Precautions for safe handling</h5>
<p>To avoid risks to human health and the environment, comply with the instructions for use. Use biocides safely. Always read the label and product information before use. Wear protective gloves. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Provide adequate ventilation. Keep container in a well-ventilated place. Avoid contact with skin, eyes and clothing.<br />
Avoid breathing vapor/spray. Do not expose to temperatures exceeding 50°C/122°F. Do not spray on an open flame or other ignition source. Keep out of the reach of children. Do not pierce or burn, even after use. Do not empty into drains. Do not eat, drink or smoke when using this product. Avoid contact with contaminated tools and objects. Do not handle broken packages without protective equipment. Wash hands thoroughly after handling.</p>
<h5>7.2. Conditions for safe storage, including any incompatibilities</h5>
<p>Store at temperatures between 4°C and 40°C. Do not expose to temperatures exceeding 50°C/122°F. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep out of the reach of children. Storage class Flammable compressed gas storage.</p>
<h5>7.3. Specific end use(s)</h5>
<p>For use as an insecticide</p>
<h4>SECTION 8: Exposure controls/personal protection</h4>
<h5>8.1. Control parameters</h5>
<p><img decoding="async" src="https://usemanuals.com/wp-content/uploads/2023/07/STV-ZER962-Live-Pes-Free-ANT-and-Crawling-Insect-Killer-User-Manual-Control-parameters.webp" /></p>
<p>PERMETHRIN (CAS: 52645-53-1)<br />
DNEL – Oral; : 16.7 – 120 mg/kg<br />
PNEC – Fresh water; 0.00000047 mg/l<br />
– STP; 0.00495 mg/l<br />
– Soil; &gt;0.0876 mg/kg<br />
– Sediment (Freshwater); 0.01 mg/kg</p>
<h5>8.2. Exposure controls</h5>
<p>If user operations generate dust, fumes, gas, vapor or mist use Process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended statutory limits.</p>
<p>Eye/face protection not normally required.<br />
Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Tight-fitting safety glasses. Personal protective equipment for eye and face protection should comply with European Standard EN166.</p>
<p>Hand protection not normally required. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. After contamination with product change gloves immediately and dispose of them according to relevant national and local regulations. Recommended : (&lt;1 hour) PVC , Nitrile gloves.</p>
<p>No personal respiratory protective equipment normally required. Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Always follow respirator manufacturer’s instructions regarding wearing and maintenance. Recommended: Full mask with type ABEK filter.</p>
<p>Steps should be taken to ensure that this product is not released accidentally into the environment.</p>
<h4>SECTION 9: Physical and chemical properties</h4>
<h5>9.1. Information on basic physical and chemical properties</h5>
<p>Appearance: Colorless aerosol<br />
Odour: Characteristic<br />
Odour threshold: Information not available<br />
pH: Information not available<br />
Melting point/freezing point: Information not available<br />
Initial boiling point and boiling range: Information not available<br />
Flash point: Information not available<br />
Evaporation rate: Information not available<br />
Flammability: Extremely flammable aerosol<br />
Upper/lower flammability or explosive limits: Information not available Vapor pressure: Information not available<br />
Vapor density: Information not available<br />
Relative density: Information not available<br />
Solubility(ies): Information not available<br />
Partition coefficient: n-octanol/water: Information not available<br />
Auto-ignition temperature: Information not available<br />
Decomposition temperature: Information not available<br />
Viscosity: Information not available<br />
Explosive properties: Information not available<br />
Oxidizing properties: Information not available</p>
<h5>9.2. Other information None</h5>
<h4>SECTION 10: Stability and reactivity</h4>
<h5>10.1. Reactivity</h5>
<p>There are no known reactivity hazards associated with this product.</p>
<h5>10.2. Chemical stability</h5>
<p>Product is stable under normal storage and handling conditions.</p>
<h5>10.3. Possibility of hazardous reactions</h5>
<p>Not determined.</p>
<h5>10.4. Conditions to avoid</h5>
<p>Avoid heat, flames and other sources of ignition.</p>
<h5>10.5. Incompatible materials</h5>
<p>No specific material or group of materials is likely to react with the product to produce a hazardous situation.</p>
<h5>10.6. Hazardous decomposition products</h5>
<p>Thermal decomposition or combustion products may include the following substances: Ammonia or amines. Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx).</p>
<h4>SECTION 11: Toxicological information</h4>
<h5>11.1. Information on toxicological effects</h5>
<p>Acute toxicity: Not expected to be toxic.<br />
Skin corrosion/irritation: Product is not classified as causing skin corrosion or irritation.<br />
Serious eye damage/irritation: Product is not classified as causing serious eye damage or irritation<br />
Respiratory or skin sensitization: The product contains a sensitizing substance. Vapors may cause<br />
headache, fatigue, dizziness and nausea<br />
Germ cell mutagenicity: No information specified.<br />
Carcinogenicity: No information specified.<br />
Reproductive toxicity: No information specified.<br />
STOT-single exposure: No information specified.<br />
STOT-repeated exposure: No information specified.<br />
Aspiration hazard: No information specified.</p>
<p>TETRAMETHRIN<br />
Acute toxicity – oral<br />
Acute toxicity oral (LD mg/kg)<br />
2,000.0<br />
Species Rat<br />
Acute toxicity – dermal<br />
Acute toxicity dermal (LD mg/kg)<br />
2,000.0 Species Rat</p>
<p>PERMETHRIN<br />
Acute toxicity – oral<br />
Acute toxicity oral (LD mg/kg)<br />
554.0<br />
Species Rat<br />
ATE oral (mg/kg) 554.0<br />
Acute toxicity – dermal<br />
Acute toxicity dermal (LD mg/kg)<br />
2,000.1</p>
<p>Species Rat<br />
ATE dermal (mg/kg)<br />
2,000.1<br />
Acute toxicity – inhalation<br />
Acute toxicity inhalation<br />
(LC dust/mist mg/l)<br />
4.638<br />
Species Rat<br />
ATE inhalation<br />
(dusts/mists mg/l)<br />
4.638</p>
<h4>SECTION 12: Ecological information</h4>
<h5>12.1. Toxicity</h5>
<p>This product is classified as very toxic to aquatic life with long lasting effects.</p>
<p>PIPERONYL BUTOXIDE<br />
Acute aquatic toxicity<br />
LE(C)₅₀ 0.1 &lt; L(E)C50 ≤ 1<br />
M factor (Acute) 1<br />
Chronic aquatic toxicity<br />
M factor (Chronic) 1</p>
<p>ATETRAMETHRIN<br />
Acute aquatic toxicity<br />
LE(C)₅₀ 0.1 &lt; L(E)C50 ≤ 1<br />
M factor (Acute) 1<br />
Acute toxicity – fish LC50, 96 hours: 0.033 mg/l, Brach danio reroof (Zebra Fish)<br />
Acute toxicity – aquatic invertebrates<br />
EC₅₀, 48 hours: 0.47 mg/l, Daphnia magna<br />
Acute toxicity – aquatic plants<br />
IC₅₀, 72 hours: 1.36 mg/l, Scenedesmus subspicatus<br />
Chronic aquatic toxicity<br />
NOEC 0.001 &lt; NOEC ≤ 0.01<br />
Degradability Non-rapidly degradable<br />
M factor (Chronic) 10</p>
<p>PERMETHRIN<br />
Acute aquatic toxicity<br />
LE(C)₅₀ 0.001 &lt; L(E)C50 ≤ 0.01<br />
M factor (Acute) 100<br />
Acute toxicity – fish LC50, 96 hours: 0.0089 mg/l, Poecilia reticulata (Guppy)<br />
LC50, 96 hours: 0.145 mg/l, Cyprinus carpio (Common carp)<br />
Acute toxicity – aquatic invertebrates<br />
EC₅₀, 48 hours: 0.02 mg/l, Daphnia magna<br />
Chronic aquatic toxicity<br />
NOEC 0.00001 &lt; NOEC ≤ 0.0001<br />
Degradability Non-rapidly degradable<br />
M factor (Chronic) 1000</p>
<h5>12.2. Persistence and degradability</h5>
<p>The product is expected to be biodegradable.</p>
<h5>12.3. Bioaccumulate potential</h5>
<p>The product does not contain any substances expected to be bioaccumulating.</p>
<h5>12.4. Mobility in soil</h5>
<p>Information not available</p>
<h5>12.5. Results of PBT and vPvB assessment</h5>
<p>This product is not identified as a PBT/vPvB substance.</p>
<h5>12.6. Other adverse effects</h5>
<p>Information not available</p>
<h4>SECTION 13: Disposal considerations</h4>
<h5>13.1. Waste treatment methods</h5>
<p>Dispose of contents/container in accordance with all local, regional, national and international regulations.</p>
<h4>SECTION 14: Transport information</h4>
<h5>14.1. UN number</h5>
<p>UN1950</p>
<h5>14.2. UN proper shipping name</h5>
<p>AEROSOLS</p>
<h5>14.3. Transport hazard class(es)</h5>
<p>2.1</p>
<h5>14.4. Packing group</h5>
<p>Not applicable.</p>
<h5>14.5. Environmental hazards</h5>
<p>Environmentally hazardous substance/marine pollutant</p>
<h5>14.6. Special precautions for user</h5>
<p>Tunnel restriction code (D)</p>
<h5>14.7. Transport in bulk according to Annex II of Marol and the IBC Code</h5>
<p>Not applicable.</p>
<h4>SECTION 15: Regulatory information</h4>
<h5>15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture</h5>
<p>This substance is classified and labelled in accordance with Regulation (EC) 1272/2008 and Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.</p>
<h5>15.2. Chemical safety assessment</h5>
<p>A Chemical Safety Assessment has not been carried out.</p>
<h4>SECTION 16: Other information</h4>
<p>ATE: Acute Toxicity Estimate.<br />
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.<br />
CAS: Chemical Abstracts Service.<br />
DNEL: Derived No Effect Level.<br />
EC₅₀: 50% of maximal Effective Concentration.<br />
IATA: International Air Transport Association.<br />
ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air.<br />
IMDG: International Maritime Dangerous Goods.<br />
LC₅₀: Lethal Concentration to 50 % of a test population.<br />
LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).<br />
NOEC: No Observed Effect Concentration.<br />
PBT: Persistent, Bioaccumulate and Toxic substance.<br />
PNEC: Predicted No Effect Concentration.<br />
REACH: Registration, Evaluation, Authorization and Restriction of Chemicals Regulation (EC) No 1907/2006.<br />
UN: United Nations.<br />
vPvB: Very Persistent and Very Bioaccumulate</p>
<p>Acute Tox. = Acute toxicity<br />
Aerosol = Aerosol<br />
Aquatic Acute = Hazardous to the aquatic environment (acute)<br />
Aquatic Chronic = Hazardous to the aquatic environment (chronic)<br />
Asp. Tox. = Aspiration hazard<br />
Press. Gas (Comp.) = Gas under pressure: Compressed gas<br />
Skin Sens. = Skin sensitization<br />
STOT SE = Specific target organ toxicity-single exposure</p>
<p>H220 Extremely flammable gas.<br />
H222 Extremely flammable aerosol.<br />
H229 Pressurized container: may burst if heated.<br />
H302 Harmful if swallowed.<br />
H317 May cause an allergic skin reaction.<br />
H332 Harmful if inhaled.<br />
H400 Very toxic to aquatic life.<br />
H410 Very toxic to aquatic life with long lasting effects.</p>
<p>Use only in accordance with label instructions.<br />
The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by legislation. The information in this data sheet should be considered when undertaking a risk assessment under the COSHH regulations. The information contained within this data sheet is strictly for general guidance only and should not be relied upon over and above this. This data sheet is intended to provide general health and safety guidance on the storage and transportation of the preparation. The information in this data sheet is accurate at the date of publication and will be updated as and when appropriate. No liability will be accepted by STV International Ltd for any loss, injury or damage arising from any failure to comply with the information and advice contained within this data sheet and/or failure to comply with the manufacturer’s guidelines, product label data and any associated technical usage literature</p>
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